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1.What is the 1,1-DIPHENYL-2-PICRYLHYDRAZINE ?
1,1-Diphenyl-2-picrylhydrazine (DPPH2) is a reduced form of the stable free radical DPPH?, formed upon reaction with radicals or reducing agents. It is widely used as a model compound in antioxidant studies, particularly in the DPPH? UV-Vis assay, which measures radical scavenging activity. The conversion of DPPH? to DPPH2 is influenced by solvent composition and the presence of reactive species, such as those generated during ultrasonic cavitation or antioxidant interactions. In ionizing solvents, DPPH? reacts via sequential proton loss electron transfer (SPLET) with phenolic compounds, while in non-ionizing solvents or acidic conditions, hydrogen atom transfer (HAT) dominates. Coordination with metals like zinc(II) can enhance radical scavenging efficiency by increasing phenol acidity and lowering bond dissociation energies. Additionally, hydrazone derivatives with hindered phenol fragments exhibit combined antioxidant effects, functioning as radical scavengers and hydroperoxide deactivators in heterogeneous systems.
1,1-Diphenyl-2-picrylhydrazine has been known to show antioxidant and anticancer properties.
2.What is the CAS number for 1,1-DIPHENYL-2-PICRYLHYDRAZINE ?
The CAS number of 1,1-DIPHENYL-2-PICRYLHYDRAZINE is 1707-75-1.
More information of 1,1-DIPHENYL-2-PICRYLHYDRAZINE 1707-75-1 are:
|
CAS?Number |
1707-75-1 |
|
Density |
1.539g/cm3 |
|
Melting Point |
~174 °C (dec.)(lit.)
|
|
Boiling Point |
530.2°Cat760mmHg |
|
Flash Point |
274.4°C |
|
Refractive Index |
1.72 |
|
HS CODE |
29280000 |
|
PSA |
152.73000 |
|
LogP |
6.21900 |
|
Pka |
-0.84±0.50(Predicted) |
3.What is the molecular formula of 1,1-DIPHENYL-2-PICRYLHYDRAZINE ?
The chemical formula of?1,1-DIPHENYL-2-PICRYLHYDRAZINE is C18H13 N5 O6 which containing 18 Carbon atoms,13 Hydrogen atoms,5 Nitrogen atoms and 6 Oxygen atoms,and the molecular weight, and the molecular weight of 1,1-DIPHENYL-2-PICRYLHYDRAZINE is 395.331
4.What is 1,1-DIPHENYL-2-PICRYLHYDRAZINE(1707-75-1)used for?
1,1-Diphenyl-2-picrylhydrazine (DPPH2) is a reduced form of the stable free radical DPPH?, formed upon reaction with radicals or reducing agents. It is widely used as a model compound in antioxidant studies, particularly in the DPPH? UV-Vis assay, which measures radical scavenging activity. The conversion of DPPH? to DPPH2 is influenced by solvent composition and the presence of reactive species, such as those generated during ultrasonic cavitation or antioxidant interactions. In ionizing solvents, DPPH? reacts via sequential proton loss electron transfer (SPLET) with phenolic compounds, while in non-ionizing solvents or acidic conditions, hydrogen atom transfer (HAT) dominates. Coordination with metals like zinc(II) can enhance radical scavenging efficiency by increasing phenol acidity and lowering bond dissociation energies. Additionally, hydrazone derivatives with hindered phenol fragments exhibit combined antioxidant effects, functioning as radical scavengers and hydroperoxide deactivators in heterogeneous systems.
InChI:InChI=1/C18H13N5O6/c19-20-15-17(22(26)27)13(11-7-3-1-4-8-11)16(21(24)25)14(18(15)23(28)29)12-9-5-2-6-10-12/h1-10,20H,19H2
Relevant articles related to 1,1-DIPHENYL-2-PICRYLHYDRAZINE:
|
Article |
Source |
|
Use of 2,2-Diphenyl-1-picrylhydrazyl To Investigate the Chemical Behavior of Free Radicals Induced by Ultrasonic Cavitation |
Sehgal, C.,Yu, T. J.,Sutherland, R. G.,Verall, R. E. , p. 2982 - 2986 (1982) |
|
Antioxidant activity of hydrazones with sterically hindered phenol fragments |
Nikolaevskii,Kniga,Khizhan,Tikhonova,Vinogradov,Khizhan , p. 1816 - 1820 (2012) |
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